서브메뉴
검색
Optical Characterization of Charge Transfer Dynamics in Photoexcited Organic Donor-Acceptor Systems
Optical Characterization of Charge Transfer Dynamics in Photoexcited Organic Donor-Acceptor Systems
상세정보
- 자료유형
- 학위논문 서양
- 최종처리일시
- 20250211152922
- ISBN
- 9798346856863
- DDC
- 540
- 서명/저자
- Optical Characterization of Charge Transfer Dynamics in Photoexcited Organic Donor-Acceptor Systems
- 발행사항
- [Sl] : Northwestern University, 2024
- 발행사항
- Ann Arbor : ProQuest Dissertations & Theses, 2024
- 형태사항
- 284 p
- 주기사항
- Source: Dissertations Abstracts International, Volume: 86-06, Section: B.
- 주기사항
- Advisor: Wasielewski, Michael R.
- 학위논문주기
- Thesis (Ph.D.)--Northwestern University, 2024.
- 초록/해제
- 요약The field of chemistry has a long history of studying charge transfer and its potential application towards addressing a myriad of problems including but not limited to solar energy harvesting, organic photovoltaic construction, and more recently, quantum information science. Organic donor-acceptor systems have been of particular interest because of their versatility and synthetic tunability. To understand the full range of applications for a system, it is important to have and implement the correct methods of instrumentation. In this work, charge transfer dynamics are studied in solution, polycrystalline film, and single crystal samples of organic donor-acceptor systems using absorption, emission, and magnetic resonance techniques. The systems studied span a wide range for this work, from charge transfer mediated singlet fission in crystalline terrylene-3,4-dicarboximide (TMI), to symmetry breaking charge separation in 1,6,7,12-tetra(4'-t-butylphenoxy)perylene(3,4:9,10) bis(dicarboximide (tpPDI), to the generation of spin correlated radical pairs via radical pair intersystem crossing in donor-chromophore-acceptor molecules such as BDX-ANI-xy-NDI, where BDX is 2,2,6,6-tetramethylbenzo[1,2-d;4,5-d]bis[1,3]dioxole, the ANI chromophore is 4-(N-piperidinyl)naphthalene-1,8-dicarboximide, the NDI acceptor is naphthalene-1,8:4,5-bis(dicarboximide), and xy is a 2,5-xylyl spacer. There are also additional details given about the construction and implementation of an optically detected magnetic resonance (ODMR) instrument. From this body of work, common threads were determined about how a variety of perturbations such as temperature, structure, and geometry effected the overall process of electron transfer. From this, each system studied can be understood and optimized towards a unique application.
- 일반주제명
- Chemistry
- 일반주제명
- Optics
- 일반주제명
- Nuclear chemistry
- 키워드
- Singlet fission
- 기타저자
- Northwestern University Chemistry
- 기본자료저록
- Dissertations Abstracts International. 86-06B.
- 전자적 위치 및 접속
- 로그인 후 원문을 볼 수 있습니다.
MARC
008250123s2024 us c eng d■001000017164198
■00520250211152922
■006m o d
■007cr#unu||||||||
■020 ▼a9798346856863
■035 ▼a(MiAaPQ)AAI31557526
■040 ▼aMiAaPQ▼cMiAaPQ
■0820 ▼a540
■1001 ▼aBrown, Paige Joann.▼0(orcid)0000-0002-2934-0098
■24510▼aOptical Characterization of Charge Transfer Dynamics in Photoexcited Organic Donor-Acceptor Systems
■260 ▼a[Sl]▼bNorthwestern University▼c2024
■260 1▼aAnn Arbor▼bProQuest Dissertations & Theses▼c2024
■300 ▼a284 p
■500 ▼aSource: Dissertations Abstracts International, Volume: 86-06, Section: B.
■500 ▼aAdvisor: Wasielewski, Michael R.
■5021 ▼aThesis (Ph.D.)--Northwestern University, 2024.
■520 ▼aThe field of chemistry has a long history of studying charge transfer and its potential application towards addressing a myriad of problems including but not limited to solar energy harvesting, organic photovoltaic construction, and more recently, quantum information science. Organic donor-acceptor systems have been of particular interest because of their versatility and synthetic tunability. To understand the full range of applications for a system, it is important to have and implement the correct methods of instrumentation. In this work, charge transfer dynamics are studied in solution, polycrystalline film, and single crystal samples of organic donor-acceptor systems using absorption, emission, and magnetic resonance techniques. The systems studied span a wide range for this work, from charge transfer mediated singlet fission in crystalline terrylene-3,4-dicarboximide (TMI), to symmetry breaking charge separation in 1,6,7,12-tetra(4'-t-butylphenoxy)perylene(3,4:9,10) bis(dicarboximide (tpPDI), to the generation of spin correlated radical pairs via radical pair intersystem crossing in donor-chromophore-acceptor molecules such as BDX-ANI-xy-NDI, where BDX is 2,2,6,6-tetramethylbenzo[1,2-d;4,5-d]bis[1,3]dioxole, the ANI chromophore is 4-(N-piperidinyl)naphthalene-1,8-dicarboximide, the NDI acceptor is naphthalene-1,8:4,5-bis(dicarboximide), and xy is a 2,5-xylyl spacer. There are also additional details given about the construction and implementation of an optically detected magnetic resonance (ODMR) instrument. From this body of work, common threads were determined about how a variety of perturbations such as temperature, structure, and geometry effected the overall process of electron transfer. From this, each system studied can be understood and optimized towards a unique application.
■590 ▼aSchool code: 0163.
■650 4▼aChemistry
■650 4▼aOptics
■650 4▼aNuclear chemistry
■653 ▼aOptically detected magnetic resonance
■653 ▼aQuantum information science
■653 ▼aSinglet fission
■653 ▼aSymmetry breaking-charge separation
■690 ▼a0485
■690 ▼a0752
■690 ▼a0738
■71020▼aNorthwestern University▼bChemistry.
■7730 ▼tDissertations Abstracts International▼g86-06B.
■790 ▼a0163
■791 ▼aPh.D.
■792 ▼a2024
■793 ▼aEnglish
■85640▼uhttp://www.riss.kr/pdu/ddodLink.do?id=T17164198▼nKERIS▼z이 자료의 원문은 한국교육학술정보원에서 제공합니다.
