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Molecular-Level Understanding of Electrode-Electrolyte Interface in Hydrogen Evolution Reaction
Molecular-Level Understanding of Electrode-Electrolyte Interface in Hydrogen Evolution Reaction
상세정보
- 자료유형
- 학위논문 서양
- 최종처리일시
- 20250211151941
- ISBN
- 9798382786032
- DDC
- 540
- 서명/저자
- Molecular-Level Understanding of Electrode-Electrolyte Interface in Hydrogen Evolution Reaction
- 발행사항
- [Sl] : University of California, Los Angeles, 2024
- 발행사항
- Ann Arbor : ProQuest Dissertations & Theses, 2024
- 형태사항
- 146 p
- 주기사항
- Source: Dissertations Abstracts International, Volume: 85-12, Section: B.
- 주기사항
- Advisor: Duan, Xiangfeng.
- 학위논문주기
- Thesis (Ph.D.)--University of California, Los Angeles, 2024.
- 초록/해제
- 요약The hydrogen evolution reaction (HER) is one of the most fundamental and critical reactions in renewable energy conversion. The recent advancement in various platinum (Pt) nanocatalyst designs has led to greatly improved HER activity. It is well recognized that the HER kinetics is drastically slower in alkaline media compared to acidic media, but the descriptors of the HER kinetics are still elusive. Specifically, in the presence of alkali metal cations and hydroxyl anions, the electrode-electrolyte (platinum-water) interface in an alkaline electrolyte is far more complex than that in an acidic electrolyte. The effects of different alkali metal cations (AM+ ) and pH on these reactions are poorly understood due to a lack of suitable experimental methods. We are combining surface-sensitive electrical transport spectroscopy (ETS) with other electrochemistry techniques and computational studies to probe and understand the fundamental role of different AM+ and pH on the reaction kinetics of HER. Our study provides fundamental insights into how and why AM+ and pH influence the HER in alkaline media. We expect that this research will provide the molecular-level understanding that will shed new insights into electrolyte engineering as an alternative pathway to control electrochemical reaction kinetics.
- 일반주제명
- Chemistry
- 일반주제명
- Energy
- 일반주제명
- Computational chemistry
- 키워드
- Electrochemistry
- 키워드
- Renewable energy
- 키워드
- Water splitting
- 기타저자
- University of California, Los Angeles Chemistry 0153
- 기본자료저록
- Dissertations Abstracts International. 85-12B.
- 전자적 위치 및 접속
- 로그인 후 원문을 볼 수 있습니다.
MARC
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■00520250211151941
■006m o d
■007cr#unu||||||||
■020 ▼a9798382786032
■035 ▼a(MiAaPQ)AAI31302228
■040 ▼aMiAaPQ▼cMiAaPQ
■0820 ▼a540
■1001 ▼aShah, Aamir Hassan.
■24510▼aMolecular-Level Understanding of Electrode-Electrolyte Interface in Hydrogen Evolution Reaction
■260 ▼a[Sl]▼bUniversity of California, Los Angeles▼c2024
■260 1▼aAnn Arbor▼bProQuest Dissertations & Theses▼c2024
■300 ▼a146 p
■500 ▼aSource: Dissertations Abstracts International, Volume: 85-12, Section: B.
■500 ▼aAdvisor: Duan, Xiangfeng.
■5021 ▼aThesis (Ph.D.)--University of California, Los Angeles, 2024.
■520 ▼aThe hydrogen evolution reaction (HER) is one of the most fundamental and critical reactions in renewable energy conversion. The recent advancement in various platinum (Pt) nanocatalyst designs has led to greatly improved HER activity. It is well recognized that the HER kinetics is drastically slower in alkaline media compared to acidic media, but the descriptors of the HER kinetics are still elusive. Specifically, in the presence of alkali metal cations and hydroxyl anions, the electrode-electrolyte (platinum-water) interface in an alkaline electrolyte is far more complex than that in an acidic electrolyte. The effects of different alkali metal cations (AM+ ) and pH on these reactions are poorly understood due to a lack of suitable experimental methods. We are combining surface-sensitive electrical transport spectroscopy (ETS) with other electrochemistry techniques and computational studies to probe and understand the fundamental role of different AM+ and pH on the reaction kinetics of HER. Our study provides fundamental insights into how and why AM+ and pH influence the HER in alkaline media. We expect that this research will provide the molecular-level understanding that will shed new insights into electrolyte engineering as an alternative pathway to control electrochemical reaction kinetics.
■590 ▼aSchool code: 0031.
■650 4▼aChemistry
■650 4▼aEnergy
■650 4▼aComputational chemistry
■653 ▼aElectrical transport spectroscopy
■653 ▼aElectrochemistry
■653 ▼aHydrogen evolution reaction
■653 ▼aInterfacial electrochemistry
■653 ▼aRenewable energy
■653 ▼aWater splitting
■690 ▼a0485
■690 ▼a0219
■690 ▼a0791
■71020▼aUniversity of California, Los Angeles▼bChemistry 0153.
■7730 ▼tDissertations Abstracts International▼g85-12B.
■790 ▼a0031
■791 ▼aPh.D.
■792 ▼a2024
■793 ▼aEnglish
■85640▼uhttp://www.riss.kr/pdu/ddodLink.do?id=T17162171▼nKERIS▼z이 자료의 원문은 한국교육학술정보원에서 제공합니다.
