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Ablation of Kapton and Carbon in Hyperthermal Atomic-Oxygen Beams
Ablation of Kapton and Carbon in Hyperthermal Atomic-Oxygen Beams
Detailed Information
- 자료유형
- 학위논문 서양
- 최종처리일시
- 20250211153039
- ISBN
- 9798346877622
- DDC
- 541
- 저자명
- Riggs, Brian E.
- 서명/저자
- Ablation of Kapton and Carbon in Hyperthermal Atomic-Oxygen Beams
- 발행사항
- [Sl] : University of Colorado at Boulder, 2024
- 발행사항
- Ann Arbor : ProQuest Dissertations & Theses, 2024
- 형태사항
- 136 p
- 주기사항
- Source: Dissertations Abstracts International, Volume: 86-06, Section: B.
- 주기사항
- Advisor: Minton, Timothy K.
- 학위논문주기
- Thesis (Ph.D.)--University of Colorado at Boulder, 2024.
- 초록/해제
- 요약Understanding the oxidation mechanisms of carbon and carbon-composite materials is key to the reliable design of heat shields for hypersonic flight through air. To gain a better understanding of the relevant gas-surface interactions, molecular beam-surface scattering experiments have been used to study reactions of O atoms on the surfaces of vitreous (glassy) carbon and a graphitic carbon (Mersen 2340) at high-temperatures. These experiments were performed with pulsed molecular beams of hyperthermal O atoms produced by a laser-detonation source. The efficiencies of the gas-surface interactions, both reactive and non-reactive, were quantified as a function of surface temperature. The angular distributions of the scattered product flux were obtained at specific temperatures, adding further insight into the thermal and non-thermal gas-surface interaction mechanisms. The molecular beam technology used in the beam-surface scattering experiments has served as the basis for a new "table-top shock tunnel (TTST)", which is intended to allow rapid and low-cost measurements of shock-layer chemistry and material response in well-characterized hypersonic flows. Initial characterization of the TTST has been conducted by exposing Kapton H samples to a hyperthermal O/O2 beam at different distances from the throat of the nozzle from which the beam emanates. The observed change in surface roughness as a function of nozzle-to-sample distance is consistent with DSMC simulations of gas compression under the experimental conditions, indicating that the high peak flux of the pulsed hyperthermal beam may lead to transient gas build-up above a test surface, producing a shock layer above the surface that is relevant to hypersonic flow environments. The TTST has been used to investigate the temperature-dependent ablation phenomenology of vitreous carbon and Mersen 2340 graphite. A comparison of the TTST and molecular beam-surface scattering results reveals complications in the TTST environment that make the interpretation of the results difficult. While the molecular beam-surface scattering experiments may be used in the development of air-carbon ablation models, an improved understanding of the ablation phenomena in the TTST will be needed before data from this apparatus may be used routinely as validation of such models that are under development.
- 일반주제명
- Physical chemistry
- 일반주제명
- Chemistry
- 일반주제명
- Aerospace engineering
- 키워드
- Atomic oxygen
- 키워드
- Carbon
- 키워드
- Hypersonic flows
- 키워드
- Low earth orbit
- 기타저자
- University of Colorado at Boulder Chemistry
- 기본자료저록
- Dissertations Abstracts International. 86-06B.
- 전자적 위치 및 접속
- 로그인 후 원문을 볼 수 있습니다.
MARC
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■00520250211153039
■006m o d
■007cr#unu||||||||
■020 ▼a9798346877622
■035 ▼a(MiAaPQ)AAI31638543
■040 ▼aMiAaPQ▼cMiAaPQ
■0820 ▼a541
■1001 ▼aRiggs, Brian E.
■24510▼aAblation of Kapton and Carbon in Hyperthermal Atomic-Oxygen Beams
■260 ▼a[Sl]▼bUniversity of Colorado at Boulder▼c2024
■260 1▼aAnn Arbor▼bProQuest Dissertations & Theses▼c2024
■300 ▼a136 p
■500 ▼aSource: Dissertations Abstracts International, Volume: 86-06, Section: B.
■500 ▼aAdvisor: Minton, Timothy K.
■5021 ▼aThesis (Ph.D.)--University of Colorado at Boulder, 2024.
■520 ▼aUnderstanding the oxidation mechanisms of carbon and carbon-composite materials is key to the reliable design of heat shields for hypersonic flight through air. To gain a better understanding of the relevant gas-surface interactions, molecular beam-surface scattering experiments have been used to study reactions of O atoms on the surfaces of vitreous (glassy) carbon and a graphitic carbon (Mersen 2340) at high-temperatures. These experiments were performed with pulsed molecular beams of hyperthermal O atoms produced by a laser-detonation source. The efficiencies of the gas-surface interactions, both reactive and non-reactive, were quantified as a function of surface temperature. The angular distributions of the scattered product flux were obtained at specific temperatures, adding further insight into the thermal and non-thermal gas-surface interaction mechanisms. The molecular beam technology used in the beam-surface scattering experiments has served as the basis for a new "table-top shock tunnel (TTST)", which is intended to allow rapid and low-cost measurements of shock-layer chemistry and material response in well-characterized hypersonic flows. Initial characterization of the TTST has been conducted by exposing Kapton H samples to a hyperthermal O/O2 beam at different distances from the throat of the nozzle from which the beam emanates. The observed change in surface roughness as a function of nozzle-to-sample distance is consistent with DSMC simulations of gas compression under the experimental conditions, indicating that the high peak flux of the pulsed hyperthermal beam may lead to transient gas build-up above a test surface, producing a shock layer above the surface that is relevant to hypersonic flow environments. The TTST has been used to investigate the temperature-dependent ablation phenomenology of vitreous carbon and Mersen 2340 graphite. A comparison of the TTST and molecular beam-surface scattering results reveals complications in the TTST environment that make the interpretation of the results difficult. While the molecular beam-surface scattering experiments may be used in the development of air-carbon ablation models, an improved understanding of the ablation phenomena in the TTST will be needed before data from this apparatus may be used routinely as validation of such models that are under development.
■590 ▼aSchool code: 0051.
■650 4▼aPhysical chemistry
■650 4▼aChemistry
■650 4▼aAerospace engineering
■653 ▼aAtomic oxygen
■653 ▼aCarbon
■653 ▼aGas-surface interactions
■653 ▼aHypersonic flows
■653 ▼aLow earth orbit
■690 ▼a0494
■690 ▼a0485
■690 ▼a0538
■71020▼aUniversity of Colorado at Boulder▼bChemistry.
■7730 ▼tDissertations Abstracts International▼g86-06B.
■790 ▼a0051
■791 ▼aPh.D.
■792 ▼a2024
■793 ▼aEnglish
■85640▼uhttp://www.riss.kr/pdu/ddodLink.do?id=T17164744▼nKERIS▼z이 자료의 원문은 한국교육학술정보원에서 제공합니다.
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