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Ablation of Kapton and Carbon in Hyperthermal Atomic-Oxygen Beams
Ablation of Kapton and Carbon in Hyperthermal Atomic-Oxygen Beams
Ablation of Kapton and Carbon in Hyperthermal Atomic-Oxygen Beams

Detailed Information

자료유형  
 학위논문 서양
최종처리일시  
20250211153039
ISBN  
9798346877622
DDC  
541
저자명  
Riggs, Brian E.
서명/저자  
Ablation of Kapton and Carbon in Hyperthermal Atomic-Oxygen Beams
발행사항  
[Sl] : University of Colorado at Boulder, 2024
발행사항  
Ann Arbor : ProQuest Dissertations & Theses, 2024
형태사항  
136 p
주기사항  
Source: Dissertations Abstracts International, Volume: 86-06, Section: B.
주기사항  
Advisor: Minton, Timothy K.
학위논문주기  
Thesis (Ph.D.)--University of Colorado at Boulder, 2024.
초록/해제  
요약Understanding the oxidation mechanisms of carbon and carbon-composite materials is key to the reliable design of heat shields for hypersonic flight through air. To gain a better understanding of the relevant gas-surface interactions, molecular beam-surface scattering experiments have been used to study reactions of O atoms on the surfaces of vitreous (glassy) carbon and a graphitic carbon (Mersen 2340) at high-temperatures. These experiments were performed with pulsed molecular beams of hyperthermal O atoms produced by a laser-detonation source. The efficiencies of the gas-surface interactions, both reactive and non-reactive, were quantified as a function of surface temperature. The angular distributions of the scattered product flux were obtained at specific temperatures, adding further insight into the thermal and non-thermal gas-surface interaction mechanisms. The molecular beam technology used in the beam-surface scattering experiments has served as the basis for a new "table-top shock tunnel (TTST)", which is intended to allow rapid and low-cost measurements of shock-layer chemistry and material response in well-characterized hypersonic flows. Initial characterization of the TTST has been conducted by exposing Kapton H samples to a hyperthermal O/O2 beam at different distances from the throat of the nozzle from which the beam emanates. The observed change in surface roughness as a function of nozzle-to-sample distance is consistent with DSMC simulations of gas compression under the experimental conditions, indicating that the high peak flux of the pulsed hyperthermal beam may lead to transient gas build-up above a test surface, producing a shock layer above the surface that is relevant to hypersonic flow environments. The TTST has been used to investigate the temperature-dependent ablation phenomenology of vitreous carbon and Mersen 2340 graphite. A comparison of the TTST and molecular beam-surface scattering results reveals complications in the TTST environment that make the interpretation of the results difficult. While the molecular beam-surface scattering experiments may be used in the development of air-carbon ablation models, an improved understanding of the ablation phenomena in the TTST will be needed before data from this apparatus may be used routinely as validation of such models that are under development.
일반주제명  
Physical chemistry
일반주제명  
Chemistry
일반주제명  
Aerospace engineering
키워드  
Atomic oxygen
키워드  
Carbon
키워드  
Gas-surface interactions
키워드  
Hypersonic flows
키워드  
Low earth orbit
기타저자  
University of Colorado at Boulder Chemistry
기본자료저록  
Dissertations Abstracts International. 86-06B.
전자적 위치 및 접속  
로그인 후 원문을 볼 수 있습니다.

MARC

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■035    ▼a(MiAaPQ)AAI31638543
■040    ▼aMiAaPQ▼cMiAaPQ
■0820  ▼a541
■1001  ▼aRiggs,  Brian  E.
■24510▼aAblation  of  Kapton  and  Carbon  in  Hyperthermal  Atomic-Oxygen  Beams
■260    ▼a[Sl]▼bUniversity  of  Colorado  at  Boulder▼c2024
■260  1▼aAnn  Arbor▼bProQuest  Dissertations  &  Theses▼c2024
■300    ▼a136  p
■500    ▼aSource:  Dissertations  Abstracts  International,  Volume:  86-06,  Section:  B.
■500    ▼aAdvisor:  Minton,  Timothy  K.
■5021  ▼aThesis  (Ph.D.)--University  of  Colorado  at  Boulder,  2024.
■520    ▼aUnderstanding  the  oxidation  mechanisms  of  carbon  and  carbon-composite  materials  is  key  to  the  reliable  design  of  heat  shields  for  hypersonic  flight  through  air.  To  gain  a  better  understanding  of  the  relevant  gas-surface  interactions,  molecular  beam-surface  scattering  experiments  have  been  used  to  study  reactions  of  O  atoms  on  the  surfaces  of  vitreous  (glassy)  carbon  and  a  graphitic  carbon  (Mersen  2340)  at  high-temperatures.  These  experiments  were  performed  with  pulsed  molecular  beams  of  hyperthermal  O  atoms  produced  by  a  laser-detonation  source.  The  efficiencies  of  the  gas-surface  interactions,  both  reactive  and  non-reactive,  were  quantified  as  a  function  of  surface  temperature.  The  angular  distributions  of  the  scattered  product  flux  were  obtained  at  specific  temperatures,  adding  further  insight  into  the  thermal  and  non-thermal  gas-surface  interaction  mechanisms.  The  molecular  beam  technology  used  in  the  beam-surface  scattering  experiments  has  served  as  the  basis  for  a  new  "table-top  shock  tunnel  (TTST)",  which  is  intended  to  allow  rapid  and  low-cost  measurements  of  shock-layer  chemistry  and  material  response  in  well-characterized  hypersonic  flows.  Initial  characterization  of  the  TTST  has  been  conducted  by  exposing  Kapton  H  samples  to  a  hyperthermal  O/O2  beam  at  different  distances  from  the  throat  of  the  nozzle  from  which  the  beam  emanates.  The  observed  change  in  surface  roughness  as  a  function  of  nozzle-to-sample  distance  is  consistent  with  DSMC  simulations  of  gas  compression  under  the  experimental  conditions,  indicating  that  the  high  peak  flux  of  the  pulsed  hyperthermal  beam  may  lead  to  transient  gas  build-up  above  a  test  surface,  producing  a  shock  layer  above  the  surface  that  is  relevant  to  hypersonic  flow  environments.  The  TTST  has  been  used  to  investigate  the  temperature-dependent  ablation  phenomenology  of  vitreous  carbon  and  Mersen  2340  graphite.  A  comparison  of  the  TTST  and  molecular  beam-surface  scattering  results  reveals  complications  in  the  TTST  environment  that  make  the  interpretation  of  the  results  difficult.  While  the  molecular  beam-surface  scattering  experiments  may  be  used  in  the  development  of  air-carbon  ablation  models,  an  improved  understanding  of  the  ablation  phenomena  in  the  TTST  will  be  needed  before  data  from  this  apparatus  may  be  used  routinely  as  validation  of  such  models  that  are  under  development.
■590    ▼aSchool  code:  0051.
■650  4▼aPhysical  chemistry
■650  4▼aChemistry
■650  4▼aAerospace  engineering
■653    ▼aAtomic  oxygen
■653    ▼aCarbon
■653    ▼aGas-surface  interactions
■653    ▼aHypersonic  flows
■653    ▼aLow  earth  orbit
■690    ▼a0494
■690    ▼a0485
■690    ▼a0538
■71020▼aUniversity  of  Colorado  at  Boulder▼bChemistry.
■7730  ▼tDissertations  Abstracts  International▼g86-06B.
■790    ▼a0051
■791    ▼aPh.D.
■792    ▼a2024
■793    ▼aEnglish
■85640▼uhttp://www.riss.kr/pdu/ddodLink.do?id=T17164744▼nKERIS▼z이  자료의  원문은  한국교육학술정보원에서  제공합니다.

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