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Characterization and Effects of Heterogeneities on Shock Compression Properties in High-Solids Loaded Additively Manufactured Polymer Composites
Characterization and Effects of Heterogeneities on Shock Compression Properties in High-Solids Loaded Additively Manufactured Polymer Composites
상세정보
- 자료유형
- 학위논문 서양
- 최종처리일시
- 20260202105554
- ISBN
- 9798263395896
- DDC
- 620.112
- 저자명
- Wagner, Karla B.
- 서명/저자
- Characterization and Effects of Heterogeneities on Shock Compression Properties in High-Solids Loaded Additively Manufactured Polymer Composites
- 발행사항
- [Sl] : Georgia Institute of Technology, 2024
- 발행사항
- Ann Arbor : ProQuest Dissertations & Theses, 2024
- 형태사항
- 188 p
- 주기사항
- Source: Dissertations Abstracts International, Volume: 87-05, Section: B.
- 주기사항
- Advisor: Thadhani, Naresh.
- 학위논문주기
- Thesis (Ph.D.)--Georgia Institute of Technology, 2024.
- 초록/해제
- 요약High-solids loaded polymer composites contain several hierarchies of heterogeneities and are of interest for use as ceramic green bodies and energetic crystals embedded in a polymer matrix. The recent and rapid growth of additive manufacturing (AM) and the engineering need for more complex geometries and individualized products has led to a surge of interest in fabricating high-loading particle composites via AM. In particular, Direct Ink Write (DIW) extrusion involving layer-by-layer deposition of a composite paste made of a high-loading of solids and a curable polymer binder is used to fabricate such composites in different geometries and forms. The layers can be deposited to form various structures, such as the colinear structure (filaments and layers are all parallel) and the log-cabin structure (filaments in a single layer are all parallel, each layer is perpendicular to the previous one). This technique is very convenient for fabricating composite structures, since the highly viscous nature of the high-solids loaded paste can be countered with the use of shear-thinning binders and there are no heat effects to consider. However, DIW-AM introduces further complexity in composites due to formation of process-inherent heterogeneities such as particle aggregation or porosities, which can be random, directional, or stochastic. The structure and composition of such materials vary across several length scales, resulting in processing and mechanical behavior that is difficult to predict or understand.Shock-compression of heterogeneous particle-filled polymer composites often involves complex interactions, which can make it difficult to predict their dynamic mechanical properties. The shock compression behavior is often dominated by mesoscale defects (including porosity) or interactions of the shock wave with interfaces and particulates. Traditional diagnostic methods, such as velocity interferometry, enable temporally-resolved measurements, but are limited in spatial resolution and generally provide volume-averaged responses. Spatially resolved measurements are therefore also necessary to provide sufficient information regarding the mesoscale processes which dominate performance of such materials. X-ray phase contrast imaging, a spatially and temporally resolved technique, in conjunction with traditional velocimetry, can enable observation of the effects of hierarchical heterogeneities on shock compression response. In this work, the effect of print geometry and porosity (process inherent heterogeneities) on the shock compression response of an additively manufactured high-solids loaded composite is studied. The composite contains three reinforcing phases: two inorganic particles and one organic particle, all with differing size distributions and morphologies. They are surrounded by a UV-curable polymer binder.In order to investigate the effect of these process inherent heterogeneities on shock response, the high-solids loaded composite's microstructure is first quantitatively characterized via microcomputed tomography imaging and computational analysis in three dimensions. Next, the composite undergoes plate-impact experiments at Argonne National Laboratory's Advanced Photon Source's Dynamic Compression Sector, with X-ray PCI used as an in-situ and in-material diagnostic. This is combined with PDV for validation. The phase contrast images are analyzed in order to measure shock and particle velocities directly from the translation of the shock wave and particles over time.Finally, the effects of print geometry, impact direction relative to print orientation, and porosity are studied by combining the aforementioned structural characterization with the shock response of the material determined via X-ray PCI. This reveals that print geometry does result in differing macroscale shock response (quantified with EOS), and that print geometry, impact orientation, and pore morphology all have an effect on microscale shock response (quantified with pore collapse velocity). We expect that these factors, only studied on a relatively small scale in this work, will become more exaggerated as sample size and therefore quantity of heterogeneities grows.
- 일반주제명
- Porosity
- 일반주제명
- Mechanical properties
- 일반주제명
- Polymers
- 일반주제명
- Tomography
- 일반주제명
- Log cabins
- 일반주제명
- Crack initiation
- 일반주제명
- Granular materials
- 일반주제명
- Crystals
- 일반주제명
- Geometry
- 일반주제명
- Ceramics
- 일반주제명
- Explosives
- 일반주제명
- Composite materials
- 일반주제명
- Industrial engineering
- 일반주제명
- Materials science
- 일반주제명
- Mechanics
- 일반주제명
- Medical imaging
- 일반주제명
- Polymer chemistry
- 기본자료저록
- Dissertations Abstracts International. 87-05B.
- 전자적 위치 및 접속
- 로그인 후 원문을 볼 수 있습니다.
MARC
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■020 ▼a9798263395896
■035 ▼a(MiAaPQ)AAI32315856
■035 ▼a(MiAaPQ)GeorgiaTech75188
■040 ▼aMiAaPQ▼cMiAaPQ
■0820 ▼a620.112
■1001 ▼aWagner, Karla B.
■24510▼aCharacterization and Effects of Heterogeneities on Shock Compression Properties in High-Solids Loaded Additively Manufactured Polymer Composites
■260 ▼a[Sl]▼bGeorgia Institute of Technology▼c2024
■260 1▼aAnn Arbor▼bProQuest Dissertations & Theses▼c2024
■300 ▼a188 p
■500 ▼aSource: Dissertations Abstracts International, Volume: 87-05, Section: B.
■500 ▼aAdvisor: Thadhani, Naresh.
■5021 ▼aThesis (Ph.D.)--Georgia Institute of Technology, 2024.
■520 ▼aHigh-solids loaded polymer composites contain several hierarchies of heterogeneities and are of interest for use as ceramic green bodies and energetic crystals embedded in a polymer matrix. The recent and rapid growth of additive manufacturing (AM) and the engineering need for more complex geometries and individualized products has led to a surge of interest in fabricating high-loading particle composites via AM. In particular, Direct Ink Write (DIW) extrusion involving layer-by-layer deposition of a composite paste made of a high-loading of solids and a curable polymer binder is used to fabricate such composites in different geometries and forms. The layers can be deposited to form various structures, such as the colinear structure (filaments and layers are all parallel) and the log-cabin structure (filaments in a single layer are all parallel, each layer is perpendicular to the previous one). This technique is very convenient for fabricating composite structures, since the highly viscous nature of the high-solids loaded paste can be countered with the use of shear-thinning binders and there are no heat effects to consider. However, DIW-AM introduces further complexity in composites due to formation of process-inherent heterogeneities such as particle aggregation or porosities, which can be random, directional, or stochastic. The structure and composition of such materials vary across several length scales, resulting in processing and mechanical behavior that is difficult to predict or understand.Shock-compression of heterogeneous particle-filled polymer composites often involves complex interactions, which can make it difficult to predict their dynamic mechanical properties. The shock compression behavior is often dominated by mesoscale defects (including porosity) or interactions of the shock wave with interfaces and particulates. Traditional diagnostic methods, such as velocity interferometry, enable temporally-resolved measurements, but are limited in spatial resolution and generally provide volume-averaged responses. Spatially resolved measurements are therefore also necessary to provide sufficient information regarding the mesoscale processes which dominate performance of such materials. X-ray phase contrast imaging, a spatially and temporally resolved technique, in conjunction with traditional velocimetry, can enable observation of the effects of hierarchical heterogeneities on shock compression response. In this work, the effect of print geometry and porosity (process inherent heterogeneities) on the shock compression response of an additively manufactured high-solids loaded composite is studied. The composite contains three reinforcing phases: two inorganic particles and one organic particle, all with differing size distributions and morphologies. They are surrounded by a UV-curable polymer binder.In order to investigate the effect of these process inherent heterogeneities on shock response, the high-solids loaded composite's microstructure is first quantitatively characterized via microcomputed tomography imaging and computational analysis in three dimensions. Next, the composite undergoes plate-impact experiments at Argonne National Laboratory's Advanced Photon Source's Dynamic Compression Sector, with X-ray PCI used as an in-situ and in-material diagnostic. This is combined with PDV for validation. The phase contrast images are analyzed in order to measure shock and particle velocities directly from the translation of the shock wave and particles over time.Finally, the effects of print geometry, impact direction relative to print orientation, and porosity are studied by combining the aforementioned structural characterization with the shock response of the material determined via X-ray PCI. This reveals that print geometry does result in differing macroscale shock response (quantified with EOS), and that print geometry, impact orientation, and pore morphology all have an effect on microscale shock response (quantified with pore collapse velocity). We expect that these factors, only studied on a relatively small scale in this work, will become more exaggerated as sample size and therefore quantity of heterogeneities grows.
■590 ▼aSchool code: 0078.
■650 4▼aPorosity
■650 4▼aMechanical properties
■650 4▼aPolymers
■650 4▼aTomography
■650 4▼aLog cabins
■650 4▼aCrack initiation
■650 4▼aGranular materials
■650 4▼aCrystals
■650 4▼aGeometry
■650 4▼aCeramics
■650 4▼aExplosives
■650 4▼aComposite materials
■650 4▼aIndustrial engineering
■650 4▼aMaterials science
■650 4▼aMechanics
■650 4▼aMedical imaging
■650 4▼aPolymer chemistry
■690 ▼a0546
■690 ▼a0794
■690 ▼a0346
■690 ▼a0574
■690 ▼a0495
■71020▼aGeorgia Institute of Technology.
■7730 ▼tDissertations Abstracts International▼g87-05B.
■790 ▼a0078
■791 ▼aPh.D.
■792 ▼a2024
■793 ▼aEnglish
■85640▼uhttp://www.riss.kr/pdu/ddodLink.do?id=T17360606▼nKERIS▼z이 자료의 원문은 한국교육학술정보원에서 제공합니다.


