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Characterization and Effects of Heterogeneities on Shock Compression Properties in High-Solids Loaded Additively Manufactured Polymer Composites
Characterization and Effects of Heterogeneities on Shock Compression Properties in High-So...
Characterization and Effects of Heterogeneities on Shock Compression Properties in High-Solids Loaded Additively Manufactured Polymer Composites

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자료유형  
 학위논문 서양
최종처리일시  
20260202105554
ISBN  
9798263395896
DDC  
620.112
저자명  
Wagner, Karla B.
서명/저자  
Characterization and Effects of Heterogeneities on Shock Compression Properties in High-Solids Loaded Additively Manufactured Polymer Composites
발행사항  
[Sl] : Georgia Institute of Technology, 2024
발행사항  
Ann Arbor : ProQuest Dissertations & Theses, 2024
형태사항  
188 p
주기사항  
Source: Dissertations Abstracts International, Volume: 87-05, Section: B.
주기사항  
Advisor: Thadhani, Naresh.
학위논문주기  
Thesis (Ph.D.)--Georgia Institute of Technology, 2024.
초록/해제  
요약High-solids loaded polymer composites contain several hierarchies of heterogeneities and are of interest for use as ceramic green bodies and energetic crystals embedded in a polymer matrix. The recent and rapid growth of additive manufacturing (AM) and the engineering need for more complex geometries and individualized products has led to a surge of interest in fabricating high-loading particle composites via AM. In particular, Direct Ink Write (DIW) extrusion involving layer-by-layer deposition of a composite paste made of a high-loading of solids and a curable polymer binder is used to fabricate such composites in different geometries and forms. The layers can be deposited to form various structures, such as the colinear structure (filaments and layers are all parallel) and the log-cabin structure (filaments in a single layer are all parallel, each layer is perpendicular to the previous one). This technique is very convenient for fabricating composite structures, since the highly viscous nature of the high-solids loaded paste can be countered with the use of shear-thinning binders and there are no heat effects to consider. However, DIW-AM introduces further complexity in composites due to formation of process-inherent heterogeneities such as particle aggregation or porosities, which can be random, directional, or stochastic. The structure and composition of such materials vary across several length scales, resulting in processing and mechanical behavior that is difficult to predict or understand.Shock-compression of heterogeneous particle-filled polymer composites often involves complex interactions, which can make it difficult to predict their dynamic mechanical properties. The shock compression behavior is often dominated by mesoscale defects (including porosity) or interactions of the shock wave with interfaces and particulates. Traditional diagnostic methods, such as velocity interferometry, enable temporally-resolved measurements, but are limited in spatial resolution and generally provide volume-averaged responses. Spatially resolved measurements are therefore also necessary to provide sufficient information regarding the mesoscale processes which dominate performance of such materials. X-ray phase contrast imaging, a spatially and temporally resolved technique, in conjunction with traditional velocimetry, can enable observation of the effects of hierarchical heterogeneities on shock compression response. In this work, the effect of print geometry and porosity (process inherent heterogeneities) on the shock compression response of an additively manufactured high-solids loaded composite is studied. The composite contains three reinforcing phases: two inorganic particles and one organic particle, all with differing size distributions and morphologies. They are surrounded by a UV-curable polymer binder.In order to investigate the effect of these process inherent heterogeneities on shock response, the high-solids loaded composite's microstructure is first quantitatively characterized via microcomputed tomography imaging and computational analysis in three dimensions. Next, the composite undergoes plate-impact experiments at Argonne National Laboratory's Advanced Photon Source's Dynamic Compression Sector, with X-ray PCI used as an in-situ and in-material diagnostic. This is combined with PDV for validation. The phase contrast images are analyzed in order to measure shock and particle velocities directly from the translation of the shock wave and particles over time.Finally, the effects of print geometry, impact direction relative to print orientation, and porosity are studied by combining the aforementioned structural characterization with the shock response of the material determined via X-ray PCI. This reveals that print geometry does result in differing macroscale shock response (quantified with EOS), and that print geometry, impact orientation, and pore morphology all have an effect on microscale shock response (quantified with pore collapse velocity). We expect that these factors, only studied on a relatively small scale in this work, will become more exaggerated as sample size and therefore quantity of heterogeneities grows.
일반주제명  
Porosity
일반주제명  
Mechanical properties
일반주제명  
Polymers
일반주제명  
Tomography
일반주제명  
Log cabins
일반주제명  
Crack initiation
일반주제명  
Granular materials
일반주제명  
Crystals
일반주제명  
Geometry
일반주제명  
Ceramics
일반주제명  
Explosives
일반주제명  
Composite materials
일반주제명  
Industrial engineering
일반주제명  
Materials science
일반주제명  
Mechanics
일반주제명  
Medical imaging
일반주제명  
Polymer chemistry
기타저자  
Georgia Institute of Technology.
기본자료저록  
Dissertations Abstracts International. 87-05B.
전자적 위치 및 접속  
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MARC

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■1001  ▼aWagner,  Karla  B.
■24510▼aCharacterization  and  Effects  of  Heterogeneities  on  Shock  Compression  Properties  in  High-Solids  Loaded  Additively  Manufactured  Polymer  Composites
■260    ▼a[Sl]▼bGeorgia  Institute  of  Technology▼c2024
■260  1▼aAnn  Arbor▼bProQuest  Dissertations  &  Theses▼c2024
■300    ▼a188  p
■500    ▼aSource:  Dissertations  Abstracts  International,  Volume:  87-05,  Section:  B.
■500    ▼aAdvisor:  Thadhani,  Naresh.
■5021  ▼aThesis  (Ph.D.)--Georgia  Institute  of  Technology,  2024.
■520    ▼aHigh-solids  loaded  polymer  composites  contain  several  hierarchies  of  heterogeneities  and  are  of  interest  for  use  as  ceramic  green  bodies  and  energetic  crystals  embedded  in  a  polymer  matrix.  The  recent  and  rapid  growth  of  additive  manufacturing  (AM)  and  the  engineering  need  for  more  complex  geometries  and  individualized  products  has  led  to  a  surge  of  interest  in  fabricating  high-loading  particle  composites  via  AM.  In  particular,  Direct  Ink  Write  (DIW)  extrusion  involving  layer-by-layer  deposition  of  a  composite  paste  made  of  a  high-loading  of  solids  and  a  curable  polymer  binder  is  used  to  fabricate  such  composites  in  different  geometries  and  forms.  The  layers  can  be  deposited  to  form  various  structures,  such  as  the  colinear  structure  (filaments  and  layers  are  all  parallel)  and  the  log-cabin  structure  (filaments  in  a  single  layer  are  all  parallel,  each  layer  is  perpendicular  to  the  previous  one).  This  technique  is  very  convenient  for  fabricating  composite  structures,  since  the  highly  viscous  nature  of  the  high-solids  loaded  paste  can  be  countered  with  the  use  of  shear-thinning  binders  and  there  are  no  heat  effects  to  consider.  However,  DIW-AM  introduces  further  complexity  in  composites  due  to  formation  of  process-inherent  heterogeneities  such  as  particle  aggregation  or  porosities,  which  can  be  random,  directional,  or  stochastic.  The  structure  and  composition  of  such  materials  vary  across  several  length  scales,  resulting  in  processing  and  mechanical  behavior  that  is  difficult  to  predict  or  understand.Shock-compression  of  heterogeneous  particle-filled  polymer  composites  often  involves  complex  interactions,  which  can  make  it  difficult  to  predict  their  dynamic  mechanical  properties.  The  shock  compression  behavior  is  often  dominated  by  mesoscale  defects  (including  porosity)  or  interactions  of  the  shock  wave  with  interfaces  and  particulates.  Traditional  diagnostic  methods,  such  as  velocity  interferometry,  enable  temporally-resolved  measurements,  but  are  limited  in  spatial  resolution  and  generally  provide  volume-averaged  responses.  Spatially  resolved  measurements  are  therefore  also  necessary  to  provide  sufficient  information  regarding  the  mesoscale  processes  which  dominate  performance  of  such  materials.  X-ray  phase  contrast  imaging,  a  spatially  and  temporally  resolved  technique,  in  conjunction  with  traditional  velocimetry,  can  enable  observation  of  the  effects  of  hierarchical  heterogeneities  on  shock  compression  response.  In  this  work,  the  effect  of  print  geometry  and  porosity  (process  inherent  heterogeneities)  on  the  shock  compression  response  of  an  additively  manufactured  high-solids  loaded  composite  is  studied.  The  composite  contains  three  reinforcing  phases:  two  inorganic  particles  and  one  organic  particle,  all  with  differing  size  distributions  and  morphologies.  They  are  surrounded  by  a  UV-curable  polymer  binder.In  order  to  investigate  the  effect  of  these  process  inherent  heterogeneities  on  shock  response,  the  high-solids  loaded  composite's  microstructure  is  first  quantitatively  characterized  via  microcomputed  tomography  imaging  and  computational  analysis  in  three  dimensions.  Next,  the  composite  undergoes  plate-impact  experiments  at  Argonne  National  Laboratory's  Advanced  Photon  Source's  Dynamic  Compression  Sector,  with  X-ray  PCI  used  as  an  in-situ  and  in-material  diagnostic.  This  is  combined  with  PDV  for  validation.  The  phase  contrast  images  are  analyzed  in  order  to  measure  shock  and  particle  velocities  directly  from  the  translation  of  the  shock  wave  and  particles  over  time.Finally,  the  effects  of  print  geometry,  impact  direction  relative  to  print  orientation,  and  porosity  are  studied  by  combining  the  aforementioned  structural  characterization  with  the  shock  response  of  the  material  determined  via  X-ray  PCI.  This  reveals  that  print  geometry  does  result  in  differing  macroscale  shock  response  (quantified  with  EOS),  and  that  print  geometry,  impact  orientation,  and  pore  morphology  all  have  an  effect  on  microscale  shock  response  (quantified  with  pore  collapse  velocity).  We  expect  that  these  factors,  only  studied  on  a  relatively  small  scale  in  this  work,  will  become  more  exaggerated  as  sample  size  and  therefore  quantity  of  heterogeneities  grows.
■590    ▼aSchool  code:  0078.
■650  4▼aPorosity
■650  4▼aMechanical  properties
■650  4▼aPolymers
■650  4▼aTomography
■650  4▼aLog  cabins
■650  4▼aCrack  initiation
■650  4▼aGranular  materials
■650  4▼aCrystals
■650  4▼aGeometry
■650  4▼aCeramics
■650  4▼aExplosives
■650  4▼aComposite  materials
■650  4▼aIndustrial  engineering
■650  4▼aMaterials  science
■650  4▼aMechanics
■650  4▼aMedical  imaging
■650  4▼aPolymer  chemistry
■690    ▼a0546
■690    ▼a0794
■690    ▼a0346
■690    ▼a0574
■690    ▼a0495
■71020▼aGeorgia  Institute  of  Technology.
■7730  ▼tDissertations  Abstracts  International▼g87-05B.
■790    ▼a0078
■791    ▼aPh.D.
■792    ▼a2024
■793    ▼aEnglish
■85640▼uhttp://www.riss.kr/pdu/ddodLink.do?id=T17360606▼nKERIS▼z이  자료의  원문은  한국교육학술정보원에서  제공합니다.

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