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Quantifying Earth's Thermal History: Advances in Cosmogenic Noble Gas Paleothermometry, Diffusion Modeling, and Evaluation of Sea-Surface Temperature Reconstructions
Quantifying Earth's Thermal History: Advances in Cosmogenic Noble Gas Paleothermometry, Di...
Quantifying Earth's Thermal History: Advances in Cosmogenic Noble Gas Paleothermometry, Diffusion Modeling, and Evaluation of Sea-Surface Temperature Reconstructions

Detailed Information

자료유형  
 학위논문 서양
최종처리일시  
20260202103132
ISBN  
9798288864438
DDC  
551
저자명  
Gorin, Andrew Louis.
서명/저자  
Quantifying Earths Thermal History: Advances in Cosmogenic Noble Gas Paleothermometry, Diffusion Modeling, and Evaluation of Sea-Surface Temperature Reconstructions
발행사항  
[Sl] : University of California, Berkeley, 2025
발행사항  
Ann Arbor : ProQuest Dissertations & Theses, 2025
형태사항  
174 p
주기사항  
Source: Dissertations Abstracts International, Volume: 87-01, Section: B.
주기사항  
Advisor: Shuster, David.
학위논문주기  
Thesis (Ph.D.)--University of California, Berkeley, 2025.
초록/해제  
요약Understanding Earth's past climate is essential for contextualizing modern climate change and refining models of future change. This dissertation advances approaches used to reconstruct terrestrial and oceanic paleotemperatures. The first study introduces the "MDD Tool Kit", a novel optimization software for constraining multiple-diffusion domain (MDD) model parameters from stepwise degassing experiments. By simultaneously optimizing all model parameters without relying on user-defined activation energies, this tool improves the accuracy of thermal history reconstructions and reveals that previous methods may systematically underestimate paleo-temperatures. Application of the toolkit to 40Ar/39Ar thermochronology data from K-feldspar in Arizona yields thermal histories 50-75◦C warmer than prior estimates, yet consistent with independent thermochronometers. The second study applies cosmogenic noble gas paleothermometry to samples from Baffin Island, Canada. Utilizing the MDD Tool Kit, this work evaluates the reliability of using single-grain diffusion kinetics to represent whole-rock behavior and investigates the influence of laboratory storage conditions on helium diffusion. Results highlight that keeping samples cold after irradiation reduces the variation in reconstructed effective diffusion temperatures, emphasizing the need for careful sample storage protocols. Further, modeling experiments show that small variations in the fit of the MDD model can result in substantial differences in inferred paleotemperatures, underscoring the intrinsic non-uniqueness of the MDD model.In the final study, this dissertation explores sea surface temperature evolution off coastal California over the past 4.2 million years using clumped isotope and δ 18O paleothermometry and compares these findings with alkenone proxy records. While prior alkenone data suggest a marked cooling trend linked to coastal upwelling intensification, the clumped and stable-isotope data show little long-term change. Detailed scanning electron microscopy reveals pervasive early diagenetic alteration in the foraminifera samples, biasing the carbonate-based proxies and raising caution for future paleoclimate studies. The findings suggest that diagenetic alteration of planktonic foraminifera during burial can occur on the scale of centuries to millennia, far faster than previously believed.These studies advance paleothermometry by refining methods, improving data reliability, and revealing methodological uncertainties, ultimately contributing to more robust reconstructions of Earth's climate history.
일반주제명  
Geochemistry
일반주제명  
Paleoclimate science
일반주제명  
Physical oceanography
일반주제명  
Climate change
키워드  
Oceanic paleotemperatures
키워드  
Thermochronometers
키워드  
Paleothermometry
키워드  
Alkenone proxy records
키워드  
Uncertainties
기타저자  
University of California, Berkeley Earth & Planetary Science
기본자료저록  
Dissertations Abstracts International. 87-01B.
전자적 위치 및 접속  
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■1001  ▼aGorin,  Andrew  Louis.
■24510▼aQuantifying  Earth's  Thermal  History:  Advances  in  Cosmogenic  Noble  Gas  Paleothermometry,  Diffusion  Modeling,  and  Evaluation  of  Sea-Surface  Temperature  Reconstructions
■260    ▼a[Sl]▼bUniversity  of  California,  Berkeley▼c2025
■260  1▼aAnn  Arbor▼bProQuest  Dissertations  &  Theses▼c2025
■300    ▼a174  p
■500    ▼aSource:  Dissertations  Abstracts  International,  Volume:  87-01,  Section:  B.
■500    ▼aAdvisor:  Shuster,  David.
■5021  ▼aThesis  (Ph.D.)--University  of  California,  Berkeley,  2025.
■520    ▼aUnderstanding  Earth's  past  climate  is  essential  for  contextualizing  modern  climate  change  and  refining  models  of  future  change.  This  dissertation  advances  approaches  used  to  reconstruct  terrestrial  and  oceanic  paleotemperatures.  The  first  study  introduces  the  "MDD  Tool  Kit",  a  novel  optimization  software  for  constraining  multiple-diffusion  domain  (MDD)  model  parameters  from  stepwise  degassing  experiments.  By  simultaneously  optimizing  all  model  parameters  without  relying  on  user-defined  activation  energies,  this  tool  improves  the  accuracy  of  thermal  history  reconstructions  and  reveals  that  previous  methods  may  systematically  underestimate  paleo-temperatures.  Application  of  the  toolkit  to  40Ar/39Ar  thermochronology  data  from  K-feldspar  in  Arizona  yields  thermal  histories  50-75◦C  warmer  than  prior  estimates,  yet  consistent  with  independent  thermochronometers. The  second  study  applies  cosmogenic  noble  gas  paleothermometry  to  samples  from  Baffin  Island,  Canada.  Utilizing  the  MDD  Tool  Kit,  this  work  evaluates  the  reliability  of  using  single-grain  diffusion  kinetics  to  represent  whole-rock  behavior  and  investigates  the  influence  of  laboratory  storage  conditions  on  helium  diffusion.  Results  highlight  that  keeping  samples  cold  after  irradiation  reduces  the  variation  in  reconstructed  effective  diffusion  temperatures,  emphasizing  the  need  for  careful  sample  storage  protocols.  Further,  modeling  experiments  show  that  small  variations  in  the  fit  of  the  MDD  model  can  result  in  substantial  differences  in  inferred  paleotemperatures,  underscoring  the  intrinsic  non-uniqueness  of  the  MDD  model.In  the  final  study,  this  dissertation  explores  sea  surface  temperature  evolution  off  coastal  California  over  the  past  4.2  million  years  using  clumped  isotope  and  δ  18O  paleothermometry  and  compares  these  findings  with  alkenone  proxy  records.  While  prior  alkenone  data  suggest  a  marked  cooling  trend  linked  to  coastal  upwelling  intensification,  the  clumped  and  stable-isotope  data  show  little  long-term  change.  Detailed  scanning  electron  microscopy  reveals  pervasive  early  diagenetic  alteration  in  the  foraminifera  samples,  biasing  the  carbonate-based  proxies  and  raising  caution  for  future  paleoclimate  studies.  The  findings  suggest  that  diagenetic  alteration  of  planktonic  foraminifera  during  burial  can  occur  on  the  scale  of  centuries  to  millennia,  far  faster  than  previously  believed.These  studies  advance  paleothermometry  by  refining  methods,  improving  data  reliability,  and  revealing  methodological  uncertainties,  ultimately  contributing  to  more  robust  reconstructions  of  Earth's  climate  history.
■590    ▼aSchool  code:  0028.
■650  4▼aGeochemistry
■650  4▼aPaleoclimate  science
■650  4▼aPhysical  oceanography
■650  4▼aClimate  change
■653    ▼aOceanic  paleotemperatures
■653    ▼aThermochronometers
■653    ▼aPaleothermometry  
■653    ▼aAlkenone  proxy  records
■653    ▼aUncertainties
■690    ▼a0996
■690    ▼a0653
■690    ▼a0415
■690    ▼a0404
■71020▼aUniversity  of  California,  Berkeley▼bEarth  &  Planetary  Science.
■7730  ▼tDissertations  Abstracts  International▼g87-01B.
■790    ▼a0028
■791    ▼aPh.D.
■792    ▼a2025
■793    ▼aEnglish
■85640▼uhttp://www.riss.kr/pdu/ddodLink.do?id=T17357108▼nKERIS▼z이  자료의  원문은  한국교육학술정보원에서  제공합니다.

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