서브메뉴
검색
Theoretical Modeling of Interactions Between Electrolytes and Surfaces
Theoretical Modeling of Interactions Between Electrolytes and Surfaces
상세정보
- 자료유형
- 학위논문 서양
- 최종처리일시
- 20260202103512
- ISBN
- 9798283487014
- DDC
- 658
- 저자명
- Bruch, Dorian.
- 서명/저자
- Theoretical Modeling of Interactions Between Electrolytes and Surfaces
- 발행사항
- [Sl] : California Institute of Technology, 2024
- 발행사항
- Ann Arbor : ProQuest Dissertations & Theses, 2024
- 형태사항
- 137 p
- 주기사항
- Source: Dissertations Abstracts International, Volume: 86-12, Section: B.
- 주기사항
- Advisor: Wang, Zhen-Gang.
- 학위논문주기
- Thesis (Ph.D.)--California Institute of Technology, 2024.
- 초록/해제
- 요약Electrolytes are ubiquitous in science and engineering and are of active interest, owing to their applications biology, energy storage, colloidal suspensions, and even climate. Near a surface, electrolyte solutions exhibit a plethora of rich thermodynamic and structural phenomena, owing to the interplay of long-ranged electrostatics and nonelectrostatic interactions between ionic species, solvent, and the surface. In this thesis, we present a pedagogical formulation for the thermodynamics of electrolyte solutions near charged surfaces, followed by an examination of interactions and structure of different types of electrolytes near surfaces. Specifically, we investigate the difference between constant surface charge and constant surface potential boundaries in electrolyte solutions, the capacitance applications, double-layer structure, and screening behavior of a zwitterionic polymers, as well as the effect of image charge on structure, capacitance, and forces in simple electrolytes near metal, dielectric, and dielectrically-saturated metal surfaces. We conclude with a Gaussian-fluctuation model for ions with soft-core excluded volume interactions.
- 일반주제명
- Behavior
- 일반주제명
- Salt
- 일반주제명
- Electrolytes
- 일반주제명
- Batteries
- 일반주제명
- Electrons
- 일반주제명
- Energy storage
- 일반주제명
- Polymer melts
- 일반주제명
- Electrodes
- 일반주제명
- Charged particles
- 일반주제명
- Solvents
- 일반주제명
- Water purification
- 일반주제명
- Atomic physics
- 일반주제명
- Energy
- 기타저자
- California Institute of Technology Chemistry and Chemical Engineering
- 기본자료저록
- Dissertations Abstracts International. 86-12B.
- 전자적 위치 및 접속
- 로그인 후 원문을 볼 수 있습니다.
MARC
008260126s2024 us c eng d■001000017357440
■00520260202103512
■006m o d
■007cr#unu||||||||
■020 ▼a9798283487014
■035 ▼a(MiAaPQ)AAI32006575
■035 ▼a(MiAaPQ)Caltech16680
■040 ▼aMiAaPQ▼cMiAaPQ
■0820 ▼a658
■1001 ▼aBruch, Dorian.
■24510▼aTheoretical Modeling of Interactions Between Electrolytes and Surfaces
■260 ▼a[Sl]▼bCalifornia Institute of Technology▼c2024
■260 1▼aAnn Arbor▼bProQuest Dissertations & Theses▼c2024
■300 ▼a137 p
■500 ▼aSource: Dissertations Abstracts International, Volume: 86-12, Section: B.
■500 ▼aAdvisor: Wang, Zhen-Gang.
■5021 ▼aThesis (Ph.D.)--California Institute of Technology, 2024.
■520 ▼aElectrolytes are ubiquitous in science and engineering and are of active interest, owing to their applications biology, energy storage, colloidal suspensions, and even climate. Near a surface, electrolyte solutions exhibit a plethora of rich thermodynamic and structural phenomena, owing to the interplay of long-ranged electrostatics and nonelectrostatic interactions between ionic species, solvent, and the surface. In this thesis, we present a pedagogical formulation for the thermodynamics of electrolyte solutions near charged surfaces, followed by an examination of interactions and structure of different types of electrolytes near surfaces. Specifically, we investigate the difference between constant surface charge and constant surface potential boundaries in electrolyte solutions, the capacitance applications, double-layer structure, and screening behavior of a zwitterionic polymers, as well as the effect of image charge on structure, capacitance, and forces in simple electrolytes near metal, dielectric, and dielectrically-saturated metal surfaces. We conclude with a Gaussian-fluctuation model for ions with soft-core excluded volume interactions.
■590 ▼aSchool code: 0037.
■650 4▼aBehavior
■650 4▼aSalt
■650 4▼aElectrolytes
■650 4▼aBatteries
■650 4▼aElectrons
■650 4▼aEnergy storage
■650 4▼aPolymer melts
■650 4▼aElectrodes
■650 4▼aCharged particles
■650 4▼aSolvents
■650 4▼aWater purification
■650 4▼aAtomic physics
■650 4▼aEnergy
■690 ▼a0748
■690 ▼a0791
■71020▼aCalifornia Institute of Technology▼bChemistry and Chemical Engineering.
■7730 ▼tDissertations Abstracts International▼g86-12B.
■790 ▼a0037
■791 ▼aPh.D.
■792 ▼a2024
■793 ▼aEnglish
■85640▼uhttp://www.riss.kr/pdu/ddodLink.do?id=T17357440▼nKERIS▼z이 자료의 원문은 한국교육학술정보원에서 제공합니다.
