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Mechanical Behavior of Nano-Architected Structures
Mechanical Behavior of Nano-Architected Structures
상세정보
- 자료유형
- 학위논문 서양
- 최종처리일시
- 20260202104738
- ISBN
- 9798290651781
- DDC
- 620.118
- 서명/저자
- Mechanical Behavior of Nano-Architected Structures
- 발행사항
- [Sl] : Stanford University, 2024
- 발행사항
- Ann Arbor : ProQuest Dissertations & Theses, 2024
- 형태사항
- 156 p
- 주기사항
- Source: Dissertations Abstracts International, Volume: 87-01, Section: B.
- 주기사항
- Advisor: Gu, Wendy.
- 학위논문주기
- Thesis (Ph.D.)--Stanford University, 2024.
- 초록/해제
- 요약Nanoscale structures and nanostructured composites can have enhanced mechanical strength and toughness. However, fabrication of complex nanoscale structures remains difficult. 3D printing methods are slow and limited to a few materials, and other methods cannot achieve arbitrary control over shape. Here, I present work on the fabrication and mechanical performance of novel nano-architected materials. First, I demonstrate a strategy for two photon lithography of complex structural nanocomposites using metal nanoclusters. These ultrasmall nanoclusters function as highly sensitive two-photon photo-initiators and simultaneously serve as mechanical reinforcers. The nanocomposites are found to have high specific strength, energy absorption, deformability, and recoverability. I further explore this material by examining the mechanical properties as a function of nanocluster concentration, strain rate, and heat treatment profile. It is found that the composite material experiences significantly more strain hardening at high strain rates which leads to high energy absorption.Then, I explore DNA origami as a means of achieving structures with a finer resolution. The best additive manufacturing techniques have resolutions of 100s of nanometers, which cannot fully realize material size effects. DNA origami is used to construct octahedral-based nanolattices, which are coated with silica. These DNA nanolattices have features two orders of magnitude smaller than additively manufactured lattices and obtain material properties comparable to the best nanolattices due to material size effects. Finite element modeling reveals two dominate failure modes: buckling at lower coating thicknesses and tensile fracture at higher thicknesses. Molecular dynamics simulations reveal that the DNA suppresses global buckling modes in favor of surface buckling, which delays failure and contributes to increased strength at large strains.Finally, I explore the colloidal self-assembly of tetrahedral particles as a means of achieving more scalable assemblies and switchable crystal structures. Simulations predict a multitude of self-assembled crystal structures from anisotropic colloids, but these shapes have been challenging to fabricate. Here, two-photon lithography is used to fabricate Archimedean truncated tetrahedrons and self-assemble them under quasi-2D confinement. These particles self-assemble into a hexagonal phase under an in-plane gravitational potential. Under additional gravitational potential, the hexagonal phase transitions into a quasi-diamond structure. In-situ imaging reveals that this phase transition is initiated by an out-of-plane rotation of a particle at a crystalline defect and causes a chain reaction of neighboring particle rotations.
- 일반주제명
- Nanocomposites
- 일반주제명
- Polymerization
- 일반주제명
- Copper
- 일반주제명
- Grain size
- 일반주제명
- Energy consumption
- 일반주제명
- Composite materials
- 일반주제명
- Crack propagation
- 일반주제명
- Polymers
- 일반주제명
- Monte Carlo simulation
- 일반주제명
- Spectrum analysis
- 일반주제명
- Fourier transforms
- 일반주제명
- Carbon
- 일반주제명
- Photochemistry
- 일반주제명
- Strain hardening
- 일반주제명
- Aluminum alloys
- 일반주제명
- Phase transitions
- 일반주제명
- Design
- 일반주제명
- Engineering
- 일반주제명
- Filler materials
- 일반주제명
- Deformation
- 일반주제명
- Density
- 일반주제명
- Geometry
- 기타저자
- Stanford University.
- 기본자료저록
- Dissertations Abstracts International. 87-01B.
- 전자적 위치 및 접속
- 로그인 후 원문을 볼 수 있습니다.
MARC
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■020 ▼a9798290651781
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■035 ▼a(MiAaPQ)Stanfordjy400rw1498
■040 ▼aMiAaPQ▼cMiAaPQ
■0820 ▼a620.118
■1001 ▼aKulikowski, John.
■24510▼aMechanical Behavior of Nano-Architected Structures
■260 ▼a[Sl]▼bStanford University▼c2024
■260 1▼aAnn Arbor▼bProQuest Dissertations & Theses▼c2024
■300 ▼a156 p
■500 ▼aSource: Dissertations Abstracts International, Volume: 87-01, Section: B.
■500 ▼aAdvisor: Gu, Wendy.
■5021 ▼aThesis (Ph.D.)--Stanford University, 2024.
■520 ▼aNanoscale structures and nanostructured composites can have enhanced mechanical strength and toughness. However, fabrication of complex nanoscale structures remains difficult. 3D printing methods are slow and limited to a few materials, and other methods cannot achieve arbitrary control over shape. Here, I present work on the fabrication and mechanical performance of novel nano-architected materials. First, I demonstrate a strategy for two photon lithography of complex structural nanocomposites using metal nanoclusters. These ultrasmall nanoclusters function as highly sensitive two-photon photo-initiators and simultaneously serve as mechanical reinforcers. The nanocomposites are found to have high specific strength, energy absorption, deformability, and recoverability. I further explore this material by examining the mechanical properties as a function of nanocluster concentration, strain rate, and heat treatment profile. It is found that the composite material experiences significantly more strain hardening at high strain rates which leads to high energy absorption.Then, I explore DNA origami as a means of achieving structures with a finer resolution. The best additive manufacturing techniques have resolutions of 100s of nanometers, which cannot fully realize material size effects. DNA origami is used to construct octahedral-based nanolattices, which are coated with silica. These DNA nanolattices have features two orders of magnitude smaller than additively manufactured lattices and obtain material properties comparable to the best nanolattices due to material size effects. Finite element modeling reveals two dominate failure modes: buckling at lower coating thicknesses and tensile fracture at higher thicknesses. Molecular dynamics simulations reveal that the DNA suppresses global buckling modes in favor of surface buckling, which delays failure and contributes to increased strength at large strains.Finally, I explore the colloidal self-assembly of tetrahedral particles as a means of achieving more scalable assemblies and switchable crystal structures. Simulations predict a multitude of self-assembled crystal structures from anisotropic colloids, but these shapes have been challenging to fabricate. Here, two-photon lithography is used to fabricate Archimedean truncated tetrahedrons and self-assemble them under quasi-2D confinement. These particles self-assemble into a hexagonal phase under an in-plane gravitational potential. Under additional gravitational potential, the hexagonal phase transitions into a quasi-diamond structure. In-situ imaging reveals that this phase transition is initiated by an out-of-plane rotation of a particle at a crystalline defect and causes a chain reaction of neighboring particle rotations.
■590 ▼aSchool code: 0212.
■650 4▼aNanocomposites
■650 4▼aPolymerization
■650 4▼aCopper
■650 4▼aGrain size
■650 4▼aEnergy consumption
■650 4▼aScanning electron microscopy
■650 4▼aComposite materials
■650 4▼aCrack propagation
■650 4▼aPolymers
■650 4▼aMonte Carlo simulation
■650 4▼aSpectrum analysis
■650 4▼aFourier transforms
■650 4▼aCarbon
■650 4▼aPhotochemistry
■650 4▼aStrain hardening
■650 4▼aAluminum alloys
■650 4▼aPhase transitions
■650 4▼aDesign
■650 4▼aEngineering
■650 4▼aFiller materials
■650 4▼aDeformation
■650 4▼aDensity
■650 4▼aGeometry
■690 ▼a0389
■690 ▼a0537
■71020▼aStanford University.
■7730 ▼tDissertations Abstracts International▼g87-01B.
■790 ▼a0212
■791 ▼aPh.D.
■792 ▼a2024
■793 ▼aEnglish
■85640▼uhttp://www.riss.kr/pdu/ddodLink.do?id=T17358691▼nKERIS▼z이 자료의 원문은 한국교육학술정보원에서 제공합니다.


