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Mechanical Behavior of Nano-Architected Structures
Mechanical Behavior of Nano-Architected Structures
Mechanical Behavior of Nano-Architected Structures

상세정보

자료유형  
 학위논문 서양
최종처리일시  
20260202104738
ISBN  
9798290651781
DDC  
620.118
저자명  
Kulikowski, John.
서명/저자  
Mechanical Behavior of Nano-Architected Structures
발행사항  
[Sl] : Stanford University, 2024
발행사항  
Ann Arbor : ProQuest Dissertations & Theses, 2024
형태사항  
156 p
주기사항  
Source: Dissertations Abstracts International, Volume: 87-01, Section: B.
주기사항  
Advisor: Gu, Wendy.
학위논문주기  
Thesis (Ph.D.)--Stanford University, 2024.
초록/해제  
요약Nanoscale structures and nanostructured composites can have enhanced mechanical strength and toughness. However, fabrication of complex nanoscale structures remains difficult. 3D printing methods are slow and limited to a few materials, and other methods cannot achieve arbitrary control over shape. Here, I present work on the fabrication and mechanical performance of novel nano-architected materials. First, I demonstrate a strategy for two photon lithography of complex structural nanocomposites using metal nanoclusters. These ultrasmall nanoclusters function as highly sensitive two-photon photo-initiators and simultaneously serve as mechanical reinforcers. The nanocomposites are found to have high specific strength, energy absorption, deformability, and recoverability. I further explore this material by examining the mechanical properties as a function of nanocluster concentration, strain rate, and heat treatment profile. It is found that the composite material experiences significantly more strain hardening at high strain rates which leads to high energy absorption.Then, I explore DNA origami as a means of achieving structures with a finer resolution. The best additive manufacturing techniques have resolutions of 100s of nanometers, which cannot fully realize material size effects. DNA origami is used to construct octahedral-based nanolattices, which are coated with silica. These DNA nanolattices have features two orders of magnitude smaller than additively manufactured lattices and obtain material properties comparable to the best nanolattices due to material size effects. Finite element modeling reveals two dominate failure modes: buckling at lower coating thicknesses and tensile fracture at higher thicknesses. Molecular dynamics simulations reveal that the DNA suppresses global buckling modes in favor of surface buckling, which delays failure and contributes to increased strength at large strains.Finally, I explore the colloidal self-assembly of tetrahedral particles as a means of achieving more scalable assemblies and switchable crystal structures. Simulations predict a multitude of self-assembled crystal structures from anisotropic colloids, but these shapes have been challenging to fabricate. Here, two-photon lithography is used to fabricate Archimedean truncated tetrahedrons and self-assemble them under quasi-2D confinement. These particles self-assemble into a hexagonal phase under an in-plane gravitational potential. Under additional gravitational potential, the hexagonal phase transitions into a quasi-diamond structure. In-situ imaging reveals that this phase transition is initiated by an out-of-plane rotation of a particle at a crystalline defect and causes a chain reaction of neighboring particle rotations.
일반주제명  
Nanocomposites
일반주제명  
Polymerization
일반주제명  
Copper
일반주제명  
Grain size
일반주제명  
Energy consumption
일반주제명  
Scanning electron microscopy
일반주제명  
Composite materials
일반주제명  
Crack propagation
일반주제명  
Polymers
일반주제명  
Monte Carlo simulation
일반주제명  
Spectrum analysis
일반주제명  
Fourier transforms
일반주제명  
Carbon
일반주제명  
Photochemistry
일반주제명  
Strain hardening
일반주제명  
Aluminum alloys
일반주제명  
Phase transitions
일반주제명  
Design
일반주제명  
Engineering
일반주제명  
Filler materials
일반주제명  
Deformation
일반주제명  
Density
일반주제명  
Geometry
기타저자  
Stanford University.
기본자료저록  
Dissertations Abstracts International. 87-01B.
전자적 위치 및 접속  
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MARC

 008260126s2024        us                              c    eng  d
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■00520260202104738
■006m          o    d                
■007cr#unu||||||||
■020    ▼a9798290651781
■035    ▼a(MiAaPQ)AAI32149675
■035    ▼a(MiAaPQ)Stanfordjy400rw1498
■040    ▼aMiAaPQ▼cMiAaPQ
■0820  ▼a620.118
■1001  ▼aKulikowski,  John.
■24510▼aMechanical  Behavior  of  Nano-Architected  Structures
■260    ▼a[Sl]▼bStanford  University▼c2024
■260  1▼aAnn  Arbor▼bProQuest  Dissertations  &  Theses▼c2024
■300    ▼a156  p
■500    ▼aSource:  Dissertations  Abstracts  International,  Volume:  87-01,  Section:  B.
■500    ▼aAdvisor:  Gu,  Wendy.
■5021  ▼aThesis  (Ph.D.)--Stanford  University,  2024.
■520    ▼aNanoscale  structures  and  nanostructured  composites  can  have  enhanced  mechanical  strength  and  toughness.  However,  fabrication  of  complex  nanoscale  structures  remains  difficult.  3D  printing  methods  are  slow  and  limited  to  a  few  materials,  and  other  methods  cannot  achieve  arbitrary  control  over  shape.  Here,  I  present  work  on  the  fabrication  and  mechanical  performance  of  novel  nano-architected  materials.  First,  I  demonstrate  a  strategy  for  two  photon  lithography  of  complex  structural  nanocomposites  using  metal  nanoclusters.  These  ultrasmall  nanoclusters  function  as  highly  sensitive  two-photon  photo-initiators  and  simultaneously  serve  as  mechanical  reinforcers.  The  nanocomposites  are  found  to  have  high  specific  strength,  energy  absorption,  deformability,  and  recoverability.  I  further  explore  this  material  by  examining  the  mechanical  properties  as  a  function  of  nanocluster  concentration,  strain  rate,  and  heat  treatment  profile.  It  is  found  that  the  composite  material  experiences  significantly  more  strain  hardening  at  high  strain  rates  which  leads  to  high  energy  absorption.Then,  I  explore  DNA  origami  as  a  means  of  achieving  structures  with  a  finer  resolution.  The  best  additive  manufacturing  techniques  have  resolutions  of  100s  of  nanometers,  which  cannot  fully  realize  material  size  effects.  DNA  origami  is  used  to  construct  octahedral-based  nanolattices,  which  are  coated  with  silica.  These  DNA  nanolattices  have  features  two  orders  of  magnitude  smaller  than  additively  manufactured  lattices  and  obtain  material  properties  comparable  to  the  best  nanolattices  due  to  material  size  effects.  Finite  element  modeling  reveals  two  dominate  failure  modes:  buckling  at  lower  coating  thicknesses  and  tensile  fracture  at  higher  thicknesses.  Molecular  dynamics  simulations  reveal  that  the  DNA  suppresses  global  buckling  modes  in  favor  of  surface  buckling,  which  delays  failure  and  contributes  to  increased  strength  at  large  strains.Finally,  I  explore  the  colloidal  self-assembly  of  tetrahedral  particles  as  a  means  of  achieving  more  scalable  assemblies  and  switchable  crystal  structures.  Simulations  predict  a  multitude  of  self-assembled  crystal  structures  from  anisotropic  colloids,  but  these  shapes  have  been  challenging  to  fabricate.  Here,  two-photon  lithography  is  used  to  fabricate  Archimedean  truncated  tetrahedrons  and  self-assemble  them  under  quasi-2D  confinement.  These  particles  self-assemble  into  a  hexagonal  phase  under  an  in-plane  gravitational  potential.  Under  additional  gravitational  potential,  the  hexagonal  phase  transitions  into  a  quasi-diamond  structure.  In-situ  imaging  reveals  that  this  phase  transition  is  initiated  by  an  out-of-plane  rotation  of  a  particle  at  a  crystalline  defect  and  causes  a  chain  reaction  of  neighboring  particle  rotations.
■590    ▼aSchool  code:  0212.
■650  4▼aNanocomposites
■650  4▼aPolymerization
■650  4▼aCopper
■650  4▼aGrain  size
■650  4▼aEnergy  consumption
■650  4▼aScanning  electron  microscopy
■650  4▼aComposite  materials
■650  4▼aCrack  propagation
■650  4▼aPolymers
■650  4▼aMonte  Carlo  simulation
■650  4▼aSpectrum  analysis
■650  4▼aFourier  transforms
■650  4▼aCarbon
■650  4▼aPhotochemistry
■650  4▼aStrain  hardening
■650  4▼aAluminum  alloys
■650  4▼aPhase  transitions
■650  4▼aDesign
■650  4▼aEngineering
■650  4▼aFiller  materials
■650  4▼aDeformation
■650  4▼aDensity
■650  4▼aGeometry
■690    ▼a0389
■690    ▼a0537
■71020▼aStanford  University.
■7730  ▼tDissertations  Abstracts  International▼g87-01B.
■790    ▼a0212
■791    ▼aPh.D.
■792    ▼a2024
■793    ▼aEnglish
■85640▼uhttp://www.riss.kr/pdu/ddodLink.do?id=T17358691▼nKERIS▼z이  자료의  원문은  한국교육학술정보원에서  제공합니다.

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