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Suppressing Intergranular Cracking in Blown Powder Laser Beam Directed Energy Deposition Additive Manufacturing of Molybdenum
Suppressing Intergranular Cracking in Blown Powder Laser Beam Directed Energy Deposition A...
Suppressing Intergranular Cracking in Blown Powder Laser Beam Directed Energy Deposition Additive Manufacturing of Molybdenum

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자료유형  
 학위논문 서양
최종처리일시  
20260202105504
ISBN  
9798263325954
DDC  
600
저자명  
Lies, Nathaniel Jay.
서명/저자  
Suppressing Intergranular Cracking in Blown Powder Laser Beam Directed Energy Deposition Additive Manufacturing of Molybdenum
발행사항  
[Sl] : Georgia Institute of Technology, 2025
발행사항  
Ann Arbor : ProQuest Dissertations & Theses, 2025
형태사항  
141 p
주기사항  
Source: Dissertations Abstracts International, Volume: 87-05, Section: B.
주기사항  
Advisor: Stebner, Aaron P.
학위논문주기  
Thesis (Ph.D.)--Georgia Institute of Technology, 2025.
초록/해제  
요약Molybdenum (Mo) alloys have long been limited in their manufacturability by low room temperature ductility and oxidation concerns. Despite these issues, Mo has found valuable application in several industries requiring high temperature structural materials, such as aerospace, nuclear power, and metalworking. The geometric freedom and atmospheric control of blown powder laser beam directed energy deposition additive manufacturing (DED-LB-BP) makes it an attractive choice for expanding applications of Mo alloys.This thesis work utilizes metallurgical insight to enable DED-LB-BP of Mo by: (1) Designing a fixture to provide repeatable solidification for the comparison of alloy properties. (2) Through use of the fixture, quantitatively showing deformation twinning in molybdenum alloys with dilute rhenium additions, explaining a decades-old discussion about the efficacy of these additions as a ductilizing agent. (3) Identifying coherent thermal expansion and contraction as the cause of intergranular cracking and stochastic fluctuations in the density of pure Mo deposits, frustrating statistical determination of a processing zone where 99% density pure Mo deposits were achieved in DED-LB-BP for the first time. (4) Evaluating three different alloying approaches to reduce intergranular cracking, reduce stochastic density fluctuation, and thereby enable the development of stable, repeatable deposition of Mo-base alloys. Of the evaluated methods, grain refinement and solid solution strengthening are shown to be the most promising candidates.Altogether, this work provides valuable insight into Mo alloys themselves, as well as directions for development of new Mo alloys to reduce intergranular cracking and enable DED-LB-BP of high temperature, complex geometry components.
일반주제명  
Metals
일반주제명  
Cold
일반주제명  
Solidification
일반주제명  
Grain boundaries
일반주제명  
Powder metallurgy
일반주제명  
Copper
일반주제명  
Energy
일반주제명  
Grain size
일반주제명  
Aerospace engineering
일반주제명  
Sintering
일반주제명  
Annealing
일반주제명  
Raw materials
일반주제명  
Segregation
일반주제명  
Solid solutions
일반주제명  
Cooling
일반주제명  
Oxidation
일반주제명  
Carbon
일반주제명  
Ductility
일반주제명  
Extrusion dies
일반주제명  
Deformation
일반주제명  
Industrial engineering
일반주제명  
Materials science
기타저자  
Georgia Institute of Technology.
기본자료저록  
Dissertations Abstracts International. 87-05B.
전자적 위치 및 접속  
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MARC

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■0820  ▼a600
■1001  ▼aLies,  Nathaniel  Jay.
■24510▼aSuppressing  Intergranular  Cracking  in  Blown  Powder  Laser  Beam  Directed  Energy  Deposition  Additive  Manufacturing  of  Molybdenum
■260    ▼a[Sl]▼bGeorgia  Institute  of  Technology▼c2025
■260  1▼aAnn  Arbor▼bProQuest  Dissertations  &  Theses▼c2025
■300    ▼a141  p
■500    ▼aSource:  Dissertations  Abstracts  International,  Volume:  87-05,  Section:  B.
■500    ▼aAdvisor:  Stebner,  Aaron  P.
■5021  ▼aThesis  (Ph.D.)--Georgia  Institute  of  Technology,  2025.
■520    ▼aMolybdenum  (Mo)  alloys  have  long  been  limited  in  their  manufacturability  by  low  room  temperature  ductility  and  oxidation  concerns.  Despite  these  issues,  Mo  has  found  valuable  application  in  several  industries  requiring  high  temperature  structural  materials,  such  as  aerospace,  nuclear  power,  and  metalworking.  The  geometric  freedom  and  atmospheric  control  of  blown  powder  laser  beam  directed  energy  deposition  additive  manufacturing  (DED-LB-BP)  makes  it  an  attractive  choice  for  expanding  applications  of  Mo  alloys.This  thesis  work  utilizes  metallurgical  insight  to  enable  DED-LB-BP  of  Mo  by:  (1)  Designing  a  fixture  to  provide  repeatable  solidification  for  the  comparison  of  alloy  properties.  (2)  Through  use  of  the  fixture,  quantitatively  showing  deformation  twinning  in  molybdenum  alloys  with  dilute  rhenium  additions,  explaining  a  decades-old  discussion  about  the  efficacy  of  these  additions  as  a  ductilizing  agent.  (3)  Identifying  coherent  thermal  expansion  and  contraction  as  the  cause  of  intergranular  cracking  and  stochastic  fluctuations  in  the  density  of  pure  Mo  deposits,  frustrating  statistical  determination  of  a  processing  zone  where  99%  density  pure  Mo  deposits  were  achieved  in  DED-LB-BP  for  the  first  time.  (4)  Evaluating  three  different  alloying  approaches  to  reduce  intergranular  cracking,  reduce  stochastic  density  fluctuation,  and  thereby  enable  the  development  of  stable,  repeatable  deposition  of  Mo-base  alloys.  Of  the  evaluated  methods,  grain  refinement  and  solid  solution  strengthening  are  shown  to  be  the  most  promising  candidates.Altogether,  this  work  provides  valuable  insight  into  Mo  alloys  themselves,  as  well  as  directions  for  development  of  new  Mo  alloys  to  reduce  intergranular  cracking  and  enable  DED-LB-BP  of  high  temperature,  complex  geometry  components.
■590    ▼aSchool  code:  0078.
■650  4▼aMetals
■650  4▼aCold
■650  4▼aSolidification
■650  4▼aGrain  boundaries
■650  4▼aPowder  metallurgy
■650  4▼aCopper
■650  4▼aEnergy
■650  4▼aGrain  size
■650  4▼aAerospace  engineering
■650  4▼aSintering
■650  4▼aAnnealing
■650  4▼aRaw  materials
■650  4▼aSegregation
■650  4▼aSolid  solutions
■650  4▼aCooling
■650  4▼aOxidation
■650  4▼aCarbon
■650  4▼aDuctility
■650  4▼aExtrusion  dies
■650  4▼aDeformation
■650  4▼aIndustrial  engineering
■650  4▼aMaterials  science
■690    ▼a0791
■690    ▼a0538
■690    ▼a0546
■690    ▼a0794
■71020▼aGeorgia  Institute  of  Technology.
■7730  ▼tDissertations  Abstracts  International▼g87-05B.
■790    ▼a0078
■791    ▼aPh.D.
■792    ▼a2025
■793    ▼aEnglish
■85640▼uhttp://www.riss.kr/pdu/ddodLink.do?id=T17360306▼nKERIS▼z이  자료의  원문은  한국교육학술정보원에서  제공합니다.

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